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36229-42-2 - 3-Chlorophenylmagnesium bromide, 1M in MeTHF - H51161 - Alfa Aesar

H51161 3-Chlorophenylmagnesium bromide, 1M in MeTHF

CAS Number
36229-42-2
Synonyms

Size Price ($) Quantity Availability
50ml 124.65
100ml 204.97
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3-Chlorophenylmagnesium bromide, 1M in MeTHF

MDL
MFCD00672003

Chemical Properties

Formula
C6H4BrClMg
Formula Weight
215.76
Sensitivity
Air & Moisture Sensitive

Applications

3-Chlorophenylmagnesium bromide is involved in the synthesis of enantiopure 2-imidazolidinones by reacting with 1,1'-DiBoc-2,2'-Biaziridine.

Notes

Air and moisture sensitive. Incompatible with strong oxidizing agents. Reacts with water.

Literature References

Murphy, C. L.; Hall, A.; Roberts, E. J.; Ryan, M. D.; Clary, J. W.; Singaram, B. Preparation and reactions of 4-iodobutyl pinacolborate. Synthesis of substituted alkyl and aryl pinacolboronates via 4-iodobutyl pinacolborate utilizing tetrahydrofuran as the leaving group. Tetrahedron Lett. 2015, 56 (23), 3032-3033.

 

Deane, K. J.; Summers, R. L.; Lehane, A. M.; Martin, R. E.; Barrow, R. A. Chlorpheniramine Analogues Reverse Chloroquine Resistance in Plasmodium falciparum by Inhibiting PfCRT. ACS Med. Chem. Lett. 2014, 5 (5), 576-581.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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