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H51162 n-Propylmagnesium chloride, 1M in MeTHF

CAS Number
2234-82-4
Synonyms

Stock No. Size Price ($) Quantity Availability
H51162-AE 100ml 58.60
H51162-AP 500ml 205.00
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n-Propylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000474

Chemical Properties

Formula
CH3CH2CH2MgCl
Formula Weight
102.85
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). Also used as reactant in Grignard-reactions for the introduction of the n-propyl group.

Notes

Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Kenneth N. Campbell; James O. Knobloch; Barbara K. Campbell. The Preparation and Some Reactions of 1,1,1-Trifluoro-2-alkenes.J. Am. Chem. Soc.,1950, 72(10), 4380-4384.

Rima S. Al-awar; Sajan P. Joseph; Daniel L. Comins. Conversion of N-acyl-2,3-dihydro-4-pyridones to 4-chloro-1,2-dihydropyridines using the Vilsmeier Reagent. Synthesis of (-)-coniine and (±)-lupinine. J. Org. Chem., 1993, 58(27), 7732-7739.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H302-H314-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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