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4-Chlorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
Boyd R.Taylor; Glenn A.Fox; Lousia J.Hope-Weeks; Robert S.Maxwell; Susan M.Kauzlarich; Howard W.H.Lee. Solution preparation of Ge nanoparticles with chemically tailored surfaces. Materials Science and Engineering: B. 2002, 96, (2),90-93
Jacqueline C.Bussolari; Patricia A.McDonnell. A new substrate for the Biginelli Cyclocondensation:? Direct preparation of 5-unsubstituted 3,4-dihydropyrimidin-2(1H)-ones from a β-keto carboxylic acid. J. Org. Chem. 2000, 65, (20),6777-6779
Hazard Statements: H225-H314-H318
Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.