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677-22-5 - tert-Butylmagnesium chloride, 1M in MeTHF - H51164 - Alfa Aesar

H51164 tert-Butylmagnesium chloride, 1M in MeTHF

CAS Number
677-22-5
Synonyms

Size Price ($) Quantity Availability
100ml 41.30
500ml 155.53
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tert-Butylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000465

Chemical Properties

Formula
C4H9ClMg
Formula Weight
116.87
Sensitivity
Air & Moisture Sensitive
Solubility
Miscible with alcohol and water.

Applications

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

Kerr, W. J.; Lindsay, D. M.; Patel, V. K.; Rajamanickam, M. Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases. Org. Biomol. Chem. 2015, 13 (40), 10131-10135.

Kamo, S.; Maruo, S.; Kuramochi, K.; Tsubaki, K. Synthesis of enantiomerically pure juglomycin C and NHAB. Tetrahedron 2015, 71 (21), 3478-3484.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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