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931-51-1 - Cyclohexylmagnesium chloride, 1M in MeTHF - H51165 - Alfa Aesar

H51165 Cyclohexylmagnesium chloride, 1M in MeTHF

CAS Number
931-51-1
Synonyms

Size Price ($) Quantity Availability
100ml 34.51
500ml 126.00
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Cyclohexylmagnesium chloride, 1M in MeTHF

MDL
MFCD00003816

Chemical Properties

Formula
C6H11ClMg
Formula Weight
142.91
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts violently with water.

Applications

Cyclohexylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is used as a reagent for the introduction of the cyclohexyl group; metalation of CH-acidic compounds.

Notes

Air & moisture sensitive. Incompatible with oxidizing agents.

Literature References

Yoshio Okamoto; Koji Ohta; Heimei Yuki. Asymmetric-selective polymerization of (RS)-α-methylbenzyl methacrylate with the cyclohexylmagnesium chloride-(---)- Sparteine system in toluene at -78°C. Macromolecules. 1978, 11, (4),724-727

Jinhwa Lee; Heejin Kim; Jin Kun Cha. A new variant of the kulinkovich hydroxycyclopropanation. Reductive coupling of carboxylic esters with terminal olefins. J. Am. Chem. Soc. 1996, 118, (17),4198-4199

 

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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