3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
Sophie Marquais; Michael Arlt. Aryl-aryl cross coupling on a solid support using zinc organic reagents and palladium catalysis. Tetrahedron Letters. 1996, 37, (31),5491-5494
Ni Yan; Xiaozhong Liu; Joseph M.Fox. Facially selective and regioselective carbometalation of cyclopropenes by Aryl Grignard Reagents. J. Org. Chem. 2008, 73, (2),563-568
Hazard Statements: H225-H302-H314-H318
Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.