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17318-03-5 - 3-Fluorophenylmagnesium bromide, 1M in MeTHF - H51168 - Alfa Aesar

H51168 3-Fluorophenylmagnesium bromide, 1M in MeTHF

CAS Number
17318-03-5
Synonyms

Size Price ($) Quantity Availability
100ml 44.70
500ml 146.40
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3-Fluorophenylmagnesium bromide, 1M in MeTHF

MDL
MFCD00672007

Chemical Properties

Formula
C6H4BrFMg
Formula Weight
199.31
Flash Point
-11°(12°F)
Density
1.024
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts violently with water.

Applications

3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Notes

Air & moisture sensitive. Incompatible with oxidizing agents, acids, bases and alcohols.

Literature References

Sophie Marquais; Michael Arlt. Aryl-aryl cross coupling on a solid support using zinc organic reagents and palladium catalysis. Tetrahedron Letters. 1996, 37, (31),5491-5494

 

Ni Yan; Xiaozhong Liu; Joseph M.Fox. Facially selective and regioselective carbometalation of cyclopropenes by Aryl Grignard Reagents. J. Org. Chem. 2008, 73, (2),563-568

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H302

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Harmful if swallowed.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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