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H51169 4-Fluorophenylmagnesium bromide, 1M in MeTHF

CAS Number

352-13-6

Synonyms

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4-Fluorophenylmagnesium bromide, 1M in MeTHF

MDL

MFCD00009667

Chemical Properties

Formula

C₆H₄BrFMg

Formula Weight

199.31

Storage & Sensitivity

Moisture Sensitive. Air Sensitive. May form a Precipitate. Ambient temperatures.

Solubility

It reacts violently with water.

Applications

4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.

Notes

Air & moisture sensitive. Incompatible with oxidizing agents.

Literature References

Namyong Y.Kim; Paul E.Laibinis. Derivatization of porous silicon by Grignard Reagents at room temperature. J. Am. Chem. Soc. 1998, 120, (18),4516-4517

K.S.Keshava Murthy; Allan W.Rey; Michael Tjepkema. Enantioselective synthesis of 3-substituted-4-aryl piperidines useful for the preparation of paroxetine. Tetrahedron Letters. 2003, 44, (28),5355-5358

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.