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2622-05-1 - Allylmagnesium chloride, 1M in MeTHF - H51170 - Alfa Aesar

H51170 Allylmagnesium chloride, 1M in MeTHF

CAS Number

Size Price ($) Quantity Availability
100ml 47.70
500ml 179.00
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Allylmagnesium chloride, 1M in MeTHF


Chemical Properties

Formula Weight
Air & Moisture Sensitive
It reacts violently with water.


Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.


Air & moisture sensitive. Stable under recommended storage conditions.

Literature References

Minglong Yuan; Dan Liu; Chengdong Xiong; Xianmo Deng. Polymerization of lactides and lactones 6. Synthesis of polydl-lactide and polyethylene glycol-co-polydl-lactide copolymer with allylmagnesium chloride. European Polymer Journal. 1999, 35, (12),21390-2145


Toshihiro Nishikawa; Hiroshi Shinokubo; Koichiro Oshima. Regioselective allylmetalation of allenes with tetraallylmanganate or allylmagnesium chloride under MnCl2 catalysis. Org. Lett. 2003, 5, (24),4623-4626

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


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