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H51170 Allylmagnesium chloride, 1M in MeTHF

CAS Number
2622-05-1
Synonyms

Stock No. Size Price ($) Quantity Availability
H51170-AE 100ml 92.10
H51170-AP 500ml 307.00
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Allylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000473

Chemical Properties

Formula
C3H5ClMg
Formula Weight
100.83
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
It reacts violently with water.

Applications

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Notes

Air & moisture sensitive. Stable under recommended storage conditions.

Literature References

Minglong Yuan; Dan Liu; Chengdong Xiong; Xianmo Deng. Polymerization of lactides and lactones 6. Synthesis of polydl-lactide and polyethylene glycol-co-polydl-lactide copolymer with allylmagnesium chloride. European Polymer Journal. 1999, 35, (12),21390-2145

 

Toshihiro Nishikawa; Hiroshi Shinokubo; Koichiro Oshima. Regioselective allylmetalation of allenes with tetraallylmanganate or allylmagnesium chloride under MnCl2 catalysis. Org. Lett. 2003, 5, (24),4623-4626

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H302-H314-H335

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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