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H51377 5-Methyl-2-(tri-n-butylstannyl)pyridine, 96%

CAS Number
189195-41-3
Synonyms
2-(Tri-n-butylstannyl)-5-methylpyridine

Stock No. Size Price ($) Quantity Availability
H51377-MD 250mg 50.60
H51377-03 1g 184.00
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5-Methyl-2-(tri-n-butylstannyl)pyridine, 96%

MDL
MFCD07787402

Chemical Properties

Formula
C18H33NSn
Formula Weight
382.16
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix.

Applications

5-Methyl-2-(tri-n-butylstannyl)pyridine is used in Stille cross coupling reactions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Guido Verniest; Xingpo Wang; Norbert De Kimpe; and Albert Padwa. Heteroaryl Cross-Coupling as an Entry toward the Synthesis of Lavendamycin Analogues: A Model Study.J. Org. Chem.,2010, 75(2), 424-433.

Yulia A. Getmanenko; and Robert J. Twieg. Unprecedented Negishi Coupling at C-Br in the Presence of a Stannyl Group as a Convenient Approach to Pyridinylstannanes and Their Application in Liquid Crystal Synthesis. J. Org. Chem., 2008, 73(3), 830-839.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H372

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P337+P313-P362-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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