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173979-01-6 - 4-(Tri-n-butylstannyl)thiazole, 95% - 4-Thiazolyltri-n-butylstannane - (Tri-n-butyl)-4-thiazolyltin - H51457 - Alfa Aesar

H51457 4-(Tri-n-butylstannyl)thiazole, 95%

CAS Number
173979-01-6
Synonyms
4-Thiazolyltri-n-butylstannane
(Tri-n-butyl)-4-thiazolyltin

Size Price ($) Quantity Availability
250mg 71.79
1g 229.69
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4-(Tri-n-butylstannyl)thiazole, 95%

MDL
MFCD01319073

Chemical Properties

Formula
C15H29NSSn
Formula Weight
374.17
Solubility
Not miscible in water.

Applications

4-(Tri-n-butylstannyl)thiazole is used as pharmaceutical intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Rudiger Wittenberg; Jiri Srogl; Masahiro Egi; Lanny S.Liebeskind. Ketone synthesis under neutral conditions. Cu(I) diphenylphosphinate-mediated, palladium-catalyzed coupling of thiol esters and organostannanes. Org. Lett. 2003, 5, (17),3033-3035

 

Hao Li; Hao Yang; Lanny S.Liebeskind. Synthesis of high enantiopurity N-Protected α-amino ketones by thiol ester-Organostannane cross-coupling using pH-neutral conditions. Org. Lett. 2008, 10, (19),4375-4378

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H372-H400-H410

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Precautionary Statements: P273-P280-P309-P310-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2934.10
TSCA
No

Recommended

  • H51455

    5-(Tri-n-butylstannyl)thiazole, 96%
  • H51531

    5-Methyl-2-(tri-n-butylstannyl)thiazole, 90+%
  • H55870

    2-(Tri-n-butylstannyl)oxazole, 96%

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