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4102-54-9 - 2-Iodo-4,6-dimethylaniline, 98% - H51875 - Alfa Aesar

H51875 2-Iodo-4,6-dimethylaniline, 98%

CAS Number
4102-54-9
Synonyms

Size Price ($) Quantity Availability
1g 53.87
5g 163.00
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2-Iodo-4,6-dimethylaniline, 98%

MDL
MFCD07779005

Chemical Properties

Formula
C8H10IN
Formula Weight
247.08
Melting point
64-65°
Sensitivity
Light Sensitive
Solubility
Insoluble in water.

Applications

It is employed in the synthesis of benzothiazoles through copper-catalyzed one-pot three-component reactions with use of sodium hydrosulfide as a sulfur surrogate.

Notes

Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark.

Literature References

Dennis P. Curran, et al. Asymmetric radical cyclization reactions of axially chiral N-allyl-o-iodoanilides to form enantioenriched N-acyl dihydroindoles.Tetrahedron.,2004,60(20), 4413-4424.

Namjin Park, et al. Synthesis of Benzothiazoles through Copper-Catalyzed One-Pot Three-Component Reactions with Use of Sodium Hydrosulfide as a Sulfur Surrogate.Eur. J. Org. Chem.,2012,2012(10), 1984-1993.

GHS Hazard and Precautionary Statements

Hazard Statements: H311-H302-H332-H315-H319

Toxic in contact with skin. Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.49
TSCA
No

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