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(S)-1,4-Diazabicyclo[4.3.0]nonane is used as stationary phases for the separation of enantiomeric mixtures of products. It is also used as catalysts for the enantioselective synthesis of various organic compounds and drugs.
Meier E.Freed; Allan R.Day. Syntheses of 1,4-Diazabicyclo[4.4.0]decanes, 1,4-Diazabicyclo[4.3.0]nonanes and 1,8-Diazabicyclo[4.3.0]nonanes. J. Org. Chem. 1960, 25, (12),2108-2113
Brian R. de Costa; Xiaoshu He; Joannes T.M.Linders; Celia Dominguez; Zi Qiang Gu; Wanda Williams; Wayne Bowen. Synthesis and evaluation of conformationally restricted N-[2-(3,4-dichlorophenyl)ethyl]-N-methyl-2-(1-pyrrolidinyl)ethylamines at .sigma. receptors. 2. Piperazines, bicyclic amines, bridged bicyclic amines, and miscellaneous compounds. J. Med. Chem. 1993, 36, (16),2311-2320
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.