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2-Bromo-3-bromomethylpyridine was obtained by reaction of the 2-bromo-3-hydroxymethylpyridine with PBr3 in dichloromethane. Reactant in the synthesis of 3-[2-bromophenyl(or pyridyl)methoxymethyl]benzo[4,5]imidazo[2,1-b]thiazoles.
Tatjana Beresneva,; Sergey Belyakov,; Edgars Abe. Palladium-Catalyzed Route To Novel Five- And Six-Cyclic Heterocyclic Systems Containing Thiazole, Imidazole And Oxepine Rings. heteroletters.org. 2012, 2 (1), 13-18.
Javier Ruiz,; Esther Lete,; Nuria Sotomayor. Intramolecular cyclisation of functionalised heteroaryllithiums. Synthesis of novel indolizinone-based compounds. Tetrahedron. 2006, 62 (26), 6182-6189.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant