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171364-83-3 - 4-Nitrobenzeneboronic acid pinacol ester, 98% - H52848 - Alfa Aesar

H52848 4-Nitrobenzeneboronic acid pinacol ester, 98%

CAS Number
171364-83-3
Synonyms

Size Price ($) Quantity Availability
1g 45.30
5g 161.00
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4-Nitrobenzeneboronic acid pinacol ester, 98%

MDL
MFCD02179437

Chemical Properties

Formula
C12H16BNO4
Formula Weight
249.08
Melting point
108-109°
Solubility
Slightly soluble in water.

Applications

4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.

Notes

Store in a cool, dry place, in a well sealed container. Store away from oxidizing agents.

Literature References

Yu Li; Lian-Xun Gao; Fu-She Han. Reliable and diverse synthesis of aryl azides through copper-catalyzed coupling of boronic acids or esters with TMSN3.. Chemistry: A European Journal. 2010, 16 (27), 7969-7972.

Aaron M Whittaker; Richard P Rucker; Gojko Lalic. Catalytic SN2'-selective substitution of allylic chlorides with arylboronic esters. Organic Letters. 2010, 12 (14), 3216-3218.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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