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H52865 4-n-Butoxybenzeneboronic acid, 98%

CAS Number
105365-51-3
Synonyms
4-n-Butoxyphenylboronic acid

Stock No. Size Price ($) Quantity Availability
H52865-03 1g 32.60
H52865-06 5g 117.00
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4-n-Butoxybenzeneboronic acid, 98%

MDL
MFCD03427054

Chemical Properties

Formula
C10H15BO3
Formula Weight
194.04
Melting point
102-104°
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

Used as a reactant for Suzuki-Miyaura cross-coupling reactions, condensation reactions, synthesis of azobenzene-functionalized compounds. Also used for preparation of highly fluorescent diketopyrrolopyrrole derivatives, rhodium-catalyzed Suzuki-type cross-coupling and copper-catalyzed asymmetric conjugate reduction of coumarins.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Elena Zaborova et. al. Cavitand supported tetraphosphine: cyclodextrin offers a useful platform for Suzuki-Miyaura cross-coupling. Chemical Communications. 2011, 47 (32), 9206-9208.

Samuel Reyes; Robert W Huigens; Zhaoming Su; Michel L Simon; Christian Melander. Synthesis and biological activity of 2-aminoimidazole triazoles accessed by Suzuki-Miyaura cross-coupling. Organic & Biomolecular Chemistry. 2011, 9 (8), 3041-3049.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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