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H52999 2-Chloro-5-(methoxycarbonyl)benzeneboronic acid, 98%

CAS Number
913835-92-4
Synonyms
Methyl 3-borono-4-chlorobenzoate
2-Chloro-5-(methoxycarbonyl)phenylboronic acid

Stock No. Size Price ($) Quantity Availability
H52999-MD 250mg 50.20
H52999-03 1g 160.00
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2-Chloro-5-(methoxycarbonyl)benzeneboronic acid, 98%

MDL
MFCD08689528

Chemical Properties

Formula
C8H8BClO4
Formula Weight
214.41
Melting point
230-232°
Storage & Sensitivity
Ambient temperatures.

Applications

Boronic acids are often used in metal-catalyzed cross-coupling for C-C, C-N bond formation, and C-H functionalization. The widely utilized Suzuki-Miyaura coupling allows for the coupling of boronic acids with carbon halides and surrogates. Other known chemistry may includes 1,4-addition to activated alkenes, 1,2-addition to carbonyls and imines, addition to anhydrides, 1,4-addition to a,ß-unsaturated ketones(4), and 1,4-addition to esters and amides.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Green, I. R.; et al. 2-Arylnaphthoquinone analogues: potential anti-TB and pro-apoptotic agents. Journal name. 2011, 192-212.

Tomohiro Yasukawa et. al.Copper-catalyzed, aerobic oxidative cross-coupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media.. Organic & Biomolecular Chemistry. 2011, 9(18), 6208-6210.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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