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127972-00-3 - 2-Methoxy-5-methylbenzeneboronic acid, 95% - H53059 - Alfa Aesar

H53059 2-Methoxy-5-methylbenzeneboronic acid, 95%

CAS Number
127972-00-3
Synonyms

Size Price ($) Quantity Availability
1g 27.00
5g 89.70
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2-Methoxy-5-methylbenzeneboronic acid, 95%

MDL
MFCD02179465

Chemical Properties

Formula
C8H11BO3
Formula Weight
165.99
Melting point
80-84°
Solubility
Soluble in methanol.

Applications

Reactant for coupling reactions, Preparation of selective quinazolinyl-phenol inhibitors of CHK1 as potential antitumors and radioprotectants, Rh-catalyzed asymmetric arylation of aldehydes, Stereoselective hydroarylation reactions, Suzuki-Miyaura cross-coupling.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Smita Rausaria et. al. Manganese(III) complexes of bis(hydroxyphenyl)dipyrromethenes are potent orally active peroxynitrite scavengers. Journal of the American Chemical Society. 2011 , 133(12), 4200-4203 .

Nishimura, T.; et al. The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes . Chem. Commun. (Camb.)2009, 5713-5715.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No
RTECS
Y

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