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18163-47-8 - 1-Iodo-2-(trimethylsilyl)acetylene, 97% - H53375 - Alfa Aesar

H53375 1-Iodo-2-(trimethylsilyl)acetylene, 97%

CAS Number
18163-47-8
Synonyms

Size Price ($) Quantity Availability
1g 27.50
5g 103.00
25g 413.03
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1-Iodo-2-(trimethylsilyl)acetylene, 97%

MDL
MFCD00274201

Chemical Properties

Formula
C5H9ISi
Formula Weight
224.12
Boiling Point
130°
Flash Point
48°(118°F)
Density
1.46
Refractive Index
1.5110
Sensitivity
Light Sensitive

Applications

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

Notes

Light sensitive. Incompatible with oxidizing agents.

Literature References

Lunhan Ding; Susan V.Olesik. Synthesis of polymer nanospheres and carbon nanospheres using the monomer 1,8-dihydroxymethyl-1,3,5,7- octatetrayne. Nano Letters. 2004, 4, (11),2271-2276

 

Elodie E.Marlier; Bridget A.Ulrich; Kristopher McNeill. Synthesis and reactivity of an isolable cobalt(I) complex containing a β-diketiminate-based acyclic tetradentate ligand. Inorg. Chem. 2012, 51, (4),2079-2085

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H332-H317-H334-H361-H226

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of damaging fertility or the unborn child. Flammable liquid and vapour.

Precautionary Statements: P210-P285-P201-P261-P280-P301+P310-P303+P361+P353-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
No

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