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H53376 4-Trimethylsilyl-3-butyn-1-ol, 98%

CAS Number
2117-12-6
Synonyms

Stock No. Size Price ($) Quantity Availability
H53376-06 5g 43.40
H53376-14 25g 172.00
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4-Trimethylsilyl-3-butyn-1-ol, 98%

MDL
MFCD00190217

Chemical Properties

Formula
C7H14OSi
Formula Weight
142.27
Boiling Point
97-98°/24mm
Flash Point
60°(140°F)
Density
0.854
Storage & Sensitivity
Ambient temperatures.

Applications

4-Trimethylsilyl-3-butyn-1-ol is used as an organic chemical synthesis intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Michel Journet; Alain Rouillard; Dongwei Cai; Robert D.Larsen. Double radical cyclization/β-fragmentation of acyclic ω-yne vinyl sulfides. Synthesis of 3-vinyldihydrothiophene and dihydrothiopyran derivatives. A new example of a 5-endo-trig radical cyclization. J. Org. Chem. 1997, 62, (25),8630-8631

 

Robert J.Hinkle; Yajing Lian; Lee C.Speight; Heather E.Stevenson; Melissa M.Sprachman; Lauren A.Katkish; M.Christa Mattern. Synthesis of 2,6-disubstituted dihydropyrans via an efficient BiBr3-initiated three component, one-pot cascade. Tetrahedron. 2009, 65, (34),6834-6839

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
No

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