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38274-16-7 - (2-Bromophenylethynyl)trimethylsilane, 98% - H53402 - Alfa Aesar

H53402 (2-Bromophenylethynyl)trimethylsilane, 98%

CAS Number
38274-16-7
Synonyms

Size Price ($) Quantity Availability
1g 20.07
5g 86.01
25g 345.05
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(2-Bromophenylethynyl)trimethylsilane, 98%

MDL
MFCD01321391

Chemical Properties

Formula
C11H13BrSi
Formula Weight
253.21
Boiling Point
60-80°/2mm
Flash Point
>113°(235°F)
Density
1.19
Refractive Index
1.554
Solubility
Slightly soluble in water.

Applications

(2-Bromophenylethynyl)trimethylsilane finds wide range application in the medicine and electronic industry. Reaction of (2-bromophenylethynyl)trimethylsilane 1 with trimethyl borate yielded the alkynearylboronic acid.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Shawn K. Collins,; Glenn P. A. Yap; Alex G. Fallis. A Novel Strained Undecadiyne Cyclophane with Interesting Dienophilic Character. ORGANIC LETTERS. 2001 , (1), 11-14.

Rolf W. Saalfran ; Martin Haubner,; Christian Deutscher,; Walter Bauer.; Timothy Clark.Cation-Mediated, Substituent-Controlled, C2-C7 Cycloaromatization of an Enyne-Allen. J. Org. Chem.. year of publication , 64 (17), 6166-6168.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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