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92136-39-5 - N-Boc-propargylamine, 97% - N-(tert-Butoxycarbonyl)propargylamine - H53406 - Alfa Aesar

H53406 N-Boc-propargylamine, 97%

CAS Number
92136-39-5
Synonyms
N-(tert-Butoxycarbonyl)propargylamine

Size Price ($) Quantity Availability
1g 22.97
5g 86.01
25g 301.50
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N-Boc-propargylamine, 97%

MDL
MFCD07367245

Chemical Properties

Formula
C8H13NO2
Formula Weight
155.20
Melting point
40-44°
Flash Point
93°(199°F)
Sensitivity
Moisture Sensitive
Solubility
Soluble in chloroform.

Applications

N-Boc-propargylamine is used to prepare triazolobenzylidene-thiazolopyrimidines. which act as CDC25 phosphatase inhibitors. Further, it is used for the synthesis of beta-glucan polysaccharide analogs. In addition to this, it is involved in the Pauson-Khand (PK) reaction of norbornadiene and N-Boc-propargylamine to prepare 4,5-disubstituted cyclopentenones .

Notes

Moisture sensitive. Incompatible with oxidizing agents. Store in a cool place.

Literature References

Kann, N.; Johansson, J. R.; Beke-Somfai, T. Conformational properties of 1, 4-and 1, 5-substituted 1, 2, 3-triazole amino acids-building units for peptidic foldamers. Org. Biomol. Chem. 2015, 13 (9), 2776-2785.

Yalagala, R. S.; Yan, H. Reactions of alkynes with trisubstituted (Z)-bromoalkenyl-pinacolboronates towards the synthesis of 1, 2, 4, 6-tetrasubstituted benzenes. Tetrahedron Lett. 2014, 55 (34), 4830-4832.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335-H402-H412

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Precautionary Statements: P261-P273-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2924.19
TSCA
No

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