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20201-24-5 - Ethyl dimethylpyruvate, 97% - Ethyl 3-methyl-2-oxobutyrate - Ketovaline ethyl ester - H53413 - Alfa Aesar

H53413 Ethyl dimethylpyruvate, 97%

CAS Number
20201-24-5
Synonyms
Ethyl 3-methyl-2-oxobutyrate
Ketovaline ethyl ester

Size Price ($) Quantity Availability
5g 36.05
25g 144.20
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Ethyl dimethylpyruvate, 97%

MDL
MFCD00009122
EINECS
243-587-0

Chemical Properties

Formula
C7H12O3
Formula Weight
144.17
Boiling Point
62°/11mm
Flash Point
43°(109°F)
Density
0.989
Refractive Index
1.410
Solubility
Slightly soluble in water.

Applications

Ethyl dimethylpyruvate is used as an allyl halide reactant in the presence of indium to release hydroxy unsaturated carbonyl compounds. It was also used in the synthesis of (2SR,4SR)-5(S)-(N-Boc)-amino-6-cyclohexyl-4-hydoxy-2-isopropyl hexanoic acid.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Alan R.Healy; Dr. Miho Izumikawa; Prof. Alexandra M.Z.Slawin; Dr. Kazuo Shin-ya; Prof. Nicholas J.Westwood. Stereochemical assignment of the protein-protein interaction inhibitor JBIR-22 by total synthesis . Angewandte Chemie International Edition. 2015, 54, (13),4046-4050

 

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1756668
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2918.30
TSCA
No

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