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931-48-6 - Cyclohexylacetylene, 98% - Ethynylcyclohexane - H53418 - Alfa Aesar

H53418 Cyclohexylacetylene, 98%

CAS Number
931-48-6
Synonyms
Ethynylcyclohexane

Size Price ($) Quantity Availability
5g 88.00
25g 336.00
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Cyclohexylacetylene, 98%

MDL
MFCD00001513
EINECS
213-236-6

Chemical Properties

Formula
C8H12
Formula Weight
108.18
Boiling Point
130-132°
Flash Point
18°(64°F)
Density
0.828
Refractive Index
1.4540
Solubility
Immiscible with water.

Applications

Cyclohexylacetylene is used in the preparation of hydrido-vinylidene complexes of osmium, which finds vital intermediates in several homogeneous and heterogeneous catalytic reactions such as alkene olimerization, polymerization and Fischer-Tropsch synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Jacquet, J.; Auvinet, A. L.; Mandadapu, A. K.; Haddad, M.; Ratovelomanana-Vidal, V.; Michelet, V. Practical Solvent-Free Ruthenium Trichloride-Mediated Benzannulation Approach to Fused Functionalized Arenes. Adv. Synth. Catal. 2015, 357 (7), 1387-1392.

Zhang, A. L.; Yang, L. W.; Yang, N. F.; Zhang, J. Synthesis of enantiopure C3-symmetric bulky trialkanolamines and their enantioselective inductivity during the alkynylation of aldehydes. J. Organomet. Chem. 2015, 775, 88-93.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1815535
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2902.19
TSCA
No

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