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16205-84-8 - Ethyl 3-(trimethylsilyl)propiolate, 98% - 3-(Trimethylsilyl)propiolic acid ethyl ester - Ethyl 3-(trimethylsilyl)propynoate - H53517 - Alfa Aesar

H53517 Ethyl 3-(trimethylsilyl)propiolate, 98%

CAS Number
16205-84-8
Synonyms
3-(Trimethylsilyl)propiolic acid ethyl ester
Ethyl 3-(trimethylsilyl)propynoate

Size Price ($) Quantity Availability
5g 36.00
25g 144.00
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Ethyl 3-(trimethylsilyl)propiolate, 98%

MDL
MFCD00074886

Chemical Properties

Formula
C8H14O2Si
Formula Weight
170.28
Boiling Point
92-96°/28mm
Flash Point
71°(160°F)
Density
0.897
Refractive Index
1.441
Solubility
Sparingly soluble in water.

Applications

Ethyl 3-(trimethylsilyl)propiolate was used in the preparation of 4-ethoxycarbonyl-3-(trimethylsilyl)furan.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Wenyuan Qian; David Winternheimer; Albert Amegadzie; Jennifer Allen. One-pot synthesis of [1,2,3]triazole-fused pyrazinopyridazindione tricycles by a ‘click and activate’ approach. Tetrahedron Letters. 2012, 53, (3),271-274

 

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1767850
Harmonized Tariff Code
2931.90
TSCA
No

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