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16205-84-8 - Ethyl 3-(trimethylsilyl)propiolate, 98% - 3-(Trimethylsilyl)propiolic acid ethyl ester - Ethyl 3-(trimethylsilyl)propynoate - H53517 - Alfa Aesar

H53517 Ethyl 3-(trimethylsilyl)propiolate, 98%

CAS Number
16205-84-8
Synonyms
3-(Trimethylsilyl)propiolic acid ethyl ester
Ethyl 3-(trimethylsilyl)propynoate

Size Price ($) Quantity Availability
5g 36.05
25g 144.20
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Ethyl 3-(trimethylsilyl)propiolate, 98%

MDL
MFCD00074886

Chemical Properties

Formula
C8H14O2Si
Formula Weight
170.28
Boiling Point
92-96°/28mm
Flash Point
71°(160°F)
Density
0.897
Refractive Index
1.441
Solubility
Sparingly soluble in water.

Applications

Ethyl 3-(trimethylsilyl)propiolate was used in the preparation of 4-ethoxycarbonyl-3-(trimethylsilyl)furan.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Wenyuan Qian; David Winternheimer; Albert Amegadzie; Jennifer Allen. One-pot synthesis of [1,2,3]triazole-fused pyrazinopyridazindione tricycles by a ‘click and activate’ approach. Tetrahedron Letters. 2012, 53, (3),271-274

 

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1767850
Harmonized Tariff Code
2931.90
TSCA
No

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