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Ethyl 3-(trimethylsilyl)propiolate was used in the preparation of 4-ethoxycarbonyl-3-(trimethylsilyl)furan.
Wenyuan Qian; David Winternheimer; Albert Amegadzie; Jennifer Allen. One-pot synthesis of [1,2,3]triazole-fused pyrazinopyridazindione tricycles by a click and activate approach. Tetrahedron Letters. 2012, 53, (3),271-274
Hazard Statements: H227-H319-H335
Combustible liquid. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P235-P261-P264b-P271-P280-P304+P340-P305+P351+P338-P312-P337+P313-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant