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34696-73-6 - 3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF - H54057 - Alfa Aesar

H54057 3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number
34696-73-6
Synonyms

Size Price ($) Quantity Availability
100ml 167.00
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3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD01311497

Chemical Properties

Formula
C8H9BrMg
Formula Weight
209.37
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts with water.

Applications

3,5-Dimethylphenylmagnesium bromide is used as pharmaceutical intermediate.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

Hidehiko Sasaki; Ryo Irie; Tetsuya Hamada; Kenji Suzuki; Tsutomu Katsuki. Rational design of Mn-salen catalyst (2): Highly enantioselective epoxidation of conjugated cis olefins. Tetrahedron. 1994, 50, (41),11827-11838

 

Derick D.Winkle; Kevin M.Schaab. Suzuki reaction of a diarylborinic acid:? One-pot preparation and cross-coupling of bis(3,5-dimethylphenyl)borinic acid. Org. Proc. Res. Dev. 2001, 5, (4),450-451

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H313-H314-H318

Highly flammable liquid and vapour. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • H54234

    5-Fluoro-2-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF
  • H54622

    3,5-Difluorophenylmagnesium bromide, 0.50M in 2-MeTHF
  • H54337

    2,5-Dimethoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

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