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H54134 2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number
34589-46-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H54134-AE 100ml 155.00
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2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD01311493

Chemical Properties

Formula
C8H9BrMg
Formula Weight
209.37
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive. May form a Precipitate. Store under Argon.
Solubility
Reacts with water.

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notes

Air and moisture sensitive. Store under inert gas. Store away from oxidizing agents, air, water/ moisture, bases, heat.

Literature References

Arthur C. Cope. The Mechanism of the Reaction of Dimethyl Sulfate with Arylmagnesium Halides. J. Am. Chem. Soc. 1934, 56 (7), 1578-1581.

W. J. Hickinbottom and N. W. Rogers. 815. Alkylation of the aromatic nucleus. Part I. The introduction of sec.-alkyl and cyclohexyl groups by reaction with esters of toluene-p-sulphonic acid. J. Chem. Soc. 1957, 4124-4130.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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