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34589-46-3 - 2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF - H54134 - Alfa Aesar

H54134 2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number
34589-46-3
Synonyms

Size Price ($) Quantity Availability
100ml 151.00
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2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD01311493

Chemical Properties

Formula
C8H9BrMg
Formula Weight
209.37
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notes

Air and moisture sensitive. Store under inert gas. Store away from oxidizing agents, air, water/ moisture, bases, heat.

Literature References

Arthur C. Cope. The Mechanism of the Reaction of Dimethyl Sulfate with Arylmagnesium Halides. J. Am. Chem. Soc. 1934, 56 (7), 1578-1581.

W. J. Hickinbottom and N. W. Rogers. 815. Alkylation of the aromatic nucleus. Part I. The introduction of sec.-alkyl and cyclohexyl groups by reaction with esters of toluene-p-sulphonic acid. J. Chem. Soc. 1957, 4124-4130.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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