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90897-92-0 - 3,4-Difluorophenylmagnesium bromide, 0.50 M in 2-MeTHF - H54197 - Alfa Aesar

H54197 3,4-Difluorophenylmagnesium bromide, 0.50 M in 2-MeTHF

CAS Number
90897-92-0
Synonyms

Size Price ($) Quantity Availability
100ml 178.00
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3,4-Difluorophenylmagnesium bromide, 0.50 M in 2-MeTHF

MDL
MFCD00672004

Chemical Properties

Formula
C6H3BrF2Mg
Formula Weight
217.29
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

3,4-Difluorophenylmagnesium bromide, 0.50 M in 2-MeTHF is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notes

Air and moisture sensitive. Store under inert gas. Store away from oxidizing agents, air, water/ moisture, bases, heat.

Literature References

Yunxiang Chen; Yangwei Huang; Xueqing Zhao; & Zhongming Lia. Concise Synthesis of 1,3-Diacetoxy-2-[2?-(2??,4??-difluorophenyl)prop-2?-en-1?-yl]propane: An Intermediate for Posaconazole. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 2015, 45 (6), 734-740.

Timothy A. Shepherd; James A. Aikins; David Bleakman; Buddy E. Cantrell; John P. Rearick; Richard L. Simon; Edward C. R. Smith; Gregory A. Stephenson; and Dennis M. Zimmerman. Design and Synthesis of a Novel Series of 1,2-Disubstituted Cyclopentanes as Small, Potent Potentiators of 2-Amino-3-(3-hydroxy-5-methyl-isoxazol-4-yl)propanoic Acid (AMPA) Receptors. J. Med. Chem. 2002, 45 (10), 2101-2111.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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