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153433-26-2 - 2-Chloro-1,3-dimethylimidazolium tetrafluoroborate, 98+% - CIB - H54316 - Alfa Aesar

H54316 2-Chloro-1,3-dimethylimidazolium tetrafluoroborate, 98+%

CAS Number

Size Price ($) Quantity Availability
1g 45.52
5g 266.77
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2-Chloro-1,3-dimethylimidazolium tetrafluoroborate, 98+%


Chemical Properties

Formula Weight
Melting point
Moisture & Light Sensitive
Soluble in acetonitrile (0.1 g/ml).


2-Chloro-1,3-dimethylimidazolium tetrafluoroborate is a reagent for esterification of C-terminal amino acids to Wang resin without racemization and for coupling α,α-dimethyl amino acids; and for preparation of the benzotriazol-1-yloxy derivative, a new coupling reagent. It is used as a reagent for esterification and peptide coupling of sterically hindered amino acids; preparation of efficient diazo-transfer reagents; oxidative insertion for palladium and nickel catalyst synthesis; and preparation of catalysts for use in coupling reactions.


Moisture and light sensitive. Incompatible with oxidizing agents and heat.

Literature References

M.Kitamura; N.Tashiro; S.Miyagawa; T.Okauchi. 2-Azido-1,3-dimethylimidazolinium salts: Efficient diazo-transfer reagents for 1,3-dicarbonyl compounds. Synthesis. 2011, (7), 1037-1044.


Doris Kremzow; Gunter Seidel; Christian W.Lehmann; Alois Furstner. Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: preparation, structure, and catalytic activity. Chemistry: A European Journal. 2005, 11,(6), 1833-1853.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code


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