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13139-86-1 - 4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF - H54317 - Alfa Aesar

H54317 4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF

CAS Number
13139-86-1
Synonyms

Size Price ($) Quantity Availability
100ml 45.94
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4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF

MDL
MFCD00013515

Chemical Properties

Formula
C7H7BrMgO
Formula Weight
211.34
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts with water.

Applications

4-Methoxyphenylmagnesium bromide is applied in Grignard-reactions as a reagent for the introduction of the 4-methoxyphenyl group.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and acids.

Literature References

Takafumi Yamagami; Ryo Shintani; Eiji Shirakawa; Tamio Hayashi. Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-Heterocyclic carbene ligand. Org. Lett. 2007, 9,(6), 1045-1048.

 

N.C.Deno; J.J.Jaruzelski; Alan Schriesheim. Carbonium ions. I. An acidity function (C0) derived from arylcarbonium ion equilibria1. J. Am. Chem. Soc. 1955, 77,(11), 3044-3051.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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