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21473-02-9 - 4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF - H54411 - Alfa Aesar

H54411 4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF

CAS Number
21473-02-9
Synonyms

Size Price ($) Quantity Availability
100ml 230.72
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4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF

MDL
MFCD00672009

Chemical Properties

Formula
C12H9BrMgO
Formula Weight
273.41
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts with water.

Applications

4-Phenoxyphenylmagnesium bromide is used as an organic chemical synthesis intermediate.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

John W.Frankenfeld; James J.Werner. Improved procedure for the Reformatsky reaction of aliphatic aldehydes and ethyl bromoacetate. J. Org. Chem. 1969, 34,(11), 3689-3691.

 

Howard M.Relles. Reaction of Grignard reagents with diphenoquinones. J. Org. Chem. 1969, 34,(11), 3687-3689.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • H54545

    9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF
  • H54579

    2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF
  • H54781

    3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

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