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H54498 Quinuclidine, 97+%

CAS Number
100-76-5
Synonyms
1-Azabicyclo[2.2.2]octane

Stock No. Size Price ($) Quantity Availability
H54498-MD 250mg 46.90
H54498-03 1g 143.00
H54498-06 5g 359.00
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Quinuclidine, 97+%

MDL
MFCD00006690
EINECS
202-887-1

Chemical Properties

Formula
C7H13N
Formula Weight
111.19
Melting point
157-160°
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in alcohol, diethyl ether, water and organic solvents.

Applications

Quinuclidine acts as a catalyst, a chemical building block and is used in organic synthesis. It is employed to prepare quinine and alkaloids. It finds application as a ligand, which is useful in the studies of OsO4-catalyzed dihydroxylation of olefins. It plays an important role in the formation of onium salts used testing of PAC-antagonist activity.

Notes

Air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and chloroformates.

Literature References

Chan, F. Y.; Sun, N.; Leung, Y. C.; Wong, K. Y. Antimicrobial activity of a quinuclidine-based FtsZ inhibitor and its synergistic potential with beta-lactam antibiotics. J. Antibiot. 2015, 68 (4), 253-258.

Reddi, Y.; Sunoj, R. B. Asymmetric Dual-Catalytic Cascade by Chiral N-Heterocyclic Carbene and Quinuclidine: Mechanism and Origin of Enantioselectivity in Benzofuranone Formation. ACS Catal. 2015, 5 (3), 1596-1603.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H310-H314-H335

Toxic if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P262-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8081
Beilstein
103111
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
CL5594625

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