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71112-64-6 - 9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF - H54545 - Alfa Aesar

H54545 9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF

CAS Number
71112-64-6
Synonyms

Size Price ($) Quantity Availability
100ml 271.92
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9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF

MDL
MFCD00672008

Chemical Properties

Formula
C14H9BrMg
Formula Weight
281.43
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts with water.

Applications

9-Phenanthrylmagnesium bromide is used as an organic chemical synthesis intermediate.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

W.E.Bachmann. Syntheses of phenanthrene derivatives. I. Reactions of 9-phenanthrylmagnesium bromide. J. Am. Chem. Soc. 1934, 56,(6), 1363-1367.

 

Harry F.Miller; G.Bryant Bachman. The higher benzenoid hydrocarbons. Syntheses with the aid of metallo derivatives1. J. Am. Chem. Soc. 1935, 57,(4), 766-771.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H313

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May be harmful in contact with skin.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

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  • H54579

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  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF
  • H54781

    3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

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