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H54632 3,4-(Methylenedioxy)phenylmagnesium bromide, 0.50 M in 2-MeTHF

CAS Number
17680-04-5
Synonyms

Stock No. Size Price ($) Quantity Availability
H54632-AE 100ml 192.00
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3,4-(Methylenedioxy)phenylmagnesium bromide, 0.50 M in 2-MeTHF

MDL
MFCD01863705

Chemical Properties

Formula
C7H5BrMgO2
Formula Weight
225.32
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
It reacts with water.

Applications

3,4-(Methylenedioxy)phenylmagnesium bromide is used as an organic chemical synthesis intermediate.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

Masahiro Bohno; Hidetomo Imasea; Noritaka Chida. A new entry to Amaryllidaceae alkaloids from carbohydrates: total synthesis of (+)-vittatine. Chem. Commun. 2004, (9), 1086-1087.

 

Stephen Hanessian; Gone Jayapal Reddy; Navjot Chahal. Total synthesis and stereochemical confirmation of manassantin A, B, and B1. Org. Lett. 2006, 8,(24), 5477-5480.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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