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H54654 3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

CAS Number
89980-69-8
Synonyms

Stock No. Size Price ($) Quantity Availability
H54654-AE 100ml 239.00
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3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

MDL
MFCD01311476

Chemical Properties

Formula
C8H9BrMgO2
Formula Weight
241.37
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive. May form a Precipitate. Store under Nitrogen.
Solubility
Reacts with water.

Applications

Used as a pharmaceutical intermediate.

Notes

Air and moisture sensitive. Air, oxidizing agents, heat are incompatible. Store under cool place.

Literature References

E. J. Corey.; Raman K. Bakshi. ; Saizo Shibata.; Chung Pin Chen.; Vinod K. Singh. A stable and easily prepared catalyst for the enantioselective reduction of ketones. Applications to multistep syntheses. J. Am. Chem. Soc. 1987, 109 (25),7925-7926.

Margaretha Van der Mey.; Armin Hatzelmann.; Ivonne J. Van der Laan.; Geert J. Sterk.; Ulrich Thibaut.; Hendrik Timmerman. Novel Selective PDE4 Inhibitors. 1. Synthesis, Structure-Activity Relationships, and Molecular Modeling of 4-(3,4-Dimethoxyphenyl)-2H-phthalazin-1-ones and Analogues. J. Med. Chem. 2001, 44 (16),2511-2522.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H300+H310+H330-H319-H335-H336-H351

Highly flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P262-P264b-P270-P271-P280i-P281-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P337+P313-P363-P37

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If eye irritation persists: Wash contaminated clothing before reuse.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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