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185416-17-5 - 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF - H54781 - Alfa Aesar

H54781 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number
185416-17-5
Synonyms

Size Price ($) Quantity Availability
100ml 276.24
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3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD13319917

Chemical Properties

Formula
C9H11BrMgO
Formula Weight
239.39
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

3,5-Dimethyl-4-methoxyphenylmagnesium bromide is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literature References

Tamio Hayashi.; Mitsuo Ishigedani. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines. Tetrahedron. 2001, 57 (13), 2589-2595.

Jin Wook Han.; Tamio Hayashi. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst. Tetrahedron: Asymmetry. 2002, 13 (3), 325-331.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • H54411

    4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF
  • H54545

    9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF
  • H54579

    2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

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