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H54781 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number

Stock No. Size Price ($) Quantity Availability
H54781-AE 100ml 270.00
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3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF


Chemical Properties

Formula Weight
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. May form a Precipitate. Store under Argon. Ambient temperatures.
Reacts with water.


3,5-Dimethyl-4-methoxyphenylmagnesium bromide is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.


Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literature References

Tamio Hayashi.; Mitsuo Ishigedani. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines. Tetrahedron. 2001, 57 (13), 2589-2595.

Jin Wook Han.; Tamio Hayashi. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst. Tetrahedron: Asymmetry. 2002, 13 (3), 325-331.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


  • H54411

    4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF
  • H54545

    9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF
  • H54579

    2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

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