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H54781 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS Number
185416-17-5
Synonyms

Stock No. Size Price ($) Quantity Availability
H54781-AE 100ml 257.00
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3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD13319917

Chemical Properties

Formula
C9H11BrMgO
Formula Weight
239.39
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. May form a Precipitate. Store under Argon. Ambient temperatures.
Solubility
Reacts with water.

Applications

3,5-Dimethyl-4-methoxyphenylmagnesium bromide is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literature References

Tamio Hayashi.; Mitsuo Ishigedani. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines. Tetrahedron. 2001, 57 (13), 2589-2595.

Jin Wook Han.; Tamio Hayashi. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst. Tetrahedron: Asymmetry. 2002, 13 (3), 325-331.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • H54411

    4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF
  • H54545

    9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF
  • H54579

    2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

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