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28276-08-6 - tert-Pentylmagnesium chloride, 1M in 2-MeTHF - 1,1-Dimethylpropylmagnesium chloride - H54824 - Alfa Aesar

H54824 tert-Pentylmagnesium chloride, 1M in 2-MeTHF

CAS Number
28276-08-6
Synonyms
1,1-Dimethylpropylmagnesium chloride

Size Price ($) Quantity Availability
100ml 212.00
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tert-Pentylmagnesium chloride, 1M in 2-MeTHF

MDL
MFCD00010356

Chemical Properties

Formula
C5H11ClMg
Formula Weight
130.90
Density
0.831
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

It is used as pharmaceutical intermediate.

Notes

Store at 4°C. Air and moisture sensitive.

Literature References

Graziano Baccolini.; Carla Boga.; Marzia Mazzacurati. Identification of a four-center intermediate in a Grignard addition reaction to a P-S bond. Tetrahedron. 2007, 63 (51),12595-12600.

Gerhard Brunner.; Laura Eberhard.; Jürg Oetiker.; Fridtjof Schröder. Tandem Cyclopropanation with Dibromomethane under Grignard Conditions. J. Org. Chem. 2008, 73 (19),7543-7554.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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