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H54865 4-Fluoro-2-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF

CAS Number
30897-90-6
Synonyms

Stock No. Size Price ($) Quantity Availability
H54865-AE 100ml 236.00
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4-Fluoro-2-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF

MDL
MFCD01311469

Chemical Properties

Formula
C7H6BrFMg
Formula Weight
213.33
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Soluble in 0.5 M in Tetrahydrofuran.

Applications

It is an important raw material and intermediate used in organic synthesis, Pharmaceuticals, agrochemicals and dyestuffs.

Notes

Store at 4°C. Air and moisture sensitive.

Literature References

Shigeo Hayashi.; Katsuyo Ohashi.; Eriko Nakata.; Chie Emoto. Discovery of 1-(β-amino substituted-β-alanyl)-N,N-dimethylindoline-2-carboxamides as novel nonpeptide antagonists of nociceptin/orphanin FQ receptor: Efficient design, synthesis, and structure-activity relationship studies.Eur. J. Med. Chem. 2012, 55 228-242.

Junya Shirai.; Hideyuki Sugiyama.; Shinji Morimoto.; Hironobu Maezaki.; Yasuharu Yamamoto.; Satoshi Okanishi.; Izumi Kamo.; Shiho Matsumoto.; Keiko Ishigami;. Nobuhiro Inatomi.; Akio Imanishi.; Makiko Kawamoto.; Naoki Tarui.; Tadatoshi Hashimoto.; Yoshinori Ikeura. Novel 3-phenylpiperidine-4-carboxamides as highly potent and orally long-acting neurokinin-1 receptor antagonists with reduced CYP3A induction. Bioorg. Med. Chem. 2012, 20 (2),962-977.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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