Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1643-73-8 - 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF - H54990 - Alfa Aesar

H54990 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF

CAS Number

Size Price ($) Quantity Availability
100ml 210.06
Add to Cart Add to Quote Request View Item

4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF


Chemical Properties

Formula Weight
Air & Moisture Sensitive
Reacts with water.


4-Fluorobenzylmagnesium chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.


Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literature References

Brian T. Gregg.; Kathryn C. Golden.; John F. Quinn.; Hong-Jun Wang.; Wei Zhang.; Ruifang Wang.; Francis Wekesa.; Dmytro O. Tymoshenko. Rapid, one-pot synthesis of α,α-disubstituted primary amines by the addition of Grignard reagents to nitriles under microwave heating conditions. Chemical Communications. 2009, 50 (27), 3978-3981.

Gang Wu.; Zhen-Wei Cai.; Mark S. Bednarz.; Octavian R. Kocy.; Ashvinikumar V. Gavai.; Jollie D. Godfrey.; William N. Washburn .; Michael A. Poss.; Philip M. Sher. Addition of Benzylic and Allylic Organozinc and Grignard Reagents to Resin-Bound Imines To Provide α-Branched Secondary Amines Bearing a Wide Variety of Functional Groups. Utility in the Synthesis of β-3 Adrenergic Receptor Agonists. J. Comb. Chem. 2005, 7 (1), 99-108.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H313

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May be harmful in contact with skin.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


  • H54966

    2,4-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF

Recently Viewed


Life Science

Metals & Materials


Analytical & Labware