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H55091 1-Naphthyl trifluoromethanesulfonate, 97%

CAS Number
99747-74-7
Synonyms
1-Naphthyl triflate

Stock No. Size Price ($) Quantity Availability
H55091-MD 250mg 13.40
H55091-03 1g 40.60
H55091-06 5g 180.00
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1-Naphthyl trifluoromethanesulfonate, 97%

MDL
MFCD00192340

Chemical Properties

Formula
C11F3H7O3S
Formula Weight
276.23
Boiling Point
97-98°/0.3mm
Flash Point
113°(235°F)
Density
1.405
Refractive Index
1.5200
Storage & Sensitivity
Ambient temperatures.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Molly E. Mowery.; Philip DeShong. Synthesis of Unsymmetrical Biaryls by Palladium-Catalyzed Cross Coupling Reactions of Arenes with Tetrabutylammonium Triphenyldifluorosilicate, a Hypervalent Silicon Reagent. J. Org. Chem. 1999, 64 (9), 3266-3270.

Dr. Carlos Vila.; Dr. Valentín Hornillos.; Massimo Giannerini.; Dr. Martín Fañanás-Mastral.; Prof. Dr. Ben L. Feringa. Palladium-Catalyzed Direct Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates. Chemistry-A European Journal,. 2014, 20 (41), 13078-13083.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.99
TSCA
No

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