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26305-75-9 - Chlorotris(triphenylphosphine)cobalt(I), 97% - H55395 - Alfa Aesar

H55395 Chlorotris(triphenylphosphine)cobalt(I), 97%

CAS Number
26305-75-9
Synonyms

Size Price ($) Quantity Availability
1g 29.87
5g 101.70
25g 370.40
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Chlorotris(triphenylphosphine)cobalt(I), 97%

MDL
MFCD00015864

Chemical Properties

Formula
C54H45ClCoP3
Formula Weight
881.26
Melting point
135-139°
Sensitivity
Air & Moisture Sensitive
Solubility
Insoluble in water.

Applications

A stoichiometric reducing agent that is used in the radical dimerization of halogenated organic molecules.

Notes

Air & Moisture Sensitive.

Literature References

Den-Ichi Momose.; Kazuo Iguchi.; Toshikazu Sugiyama.; Yasuji Yamada. Reductive coupling of allylic halides by chlorotris(triphenylphosphine)cobalt(I).Tetrahedron Lett. 1983, 24 (9),921-924.

Den-ichi Momose.; Yasuji Yamada. Reaction of bromohydrins with chlorotris(triphenylphosphine)cobalt (I). Tetrahedron Lett. 1983, 24 (26),2669-2672.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P280-P264-P270-P304+P340-P301+P312-P312-P363-P322-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific measures (see label). Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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