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13139-86-1 - 4-Methoxyphenylmagnesium bromide, 0.25M in THF - 4-Anisylmagnesium bromide - H55397 - Alfa Aesar

H55397 4-Methoxyphenylmagnesium bromide, 0.25M in THF

CAS Number
13139-86-1
Synonyms
4-Anisylmagnesium bromide

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4-Methoxyphenylmagnesium bromide, 0.25M in THF

MDL
MFCD00013515

Chemical Properties

Formula
C7H7BrMgO
Formula Weight
211.34
Flash Point
-20°(-4°F)
Density
0.955
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Used as pharmaceutical intermediate.

Notes

Air & Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Charles D. Jones.; Tulio Suarez.; Eddie H. Massey.; Larry J. Black.; Frank C. Tinsley. Synthesis and antiestrogenic activity of [3,4-dihydro-2-(4-methoxyphenyl)-1-naphthalenyl][4-[2-(1-pyrrolidinyl)ethoxy]phenyl]methanone, methanesulfonic acid salt. J. Med. Chem. 1979, 22, (8), 962-966.

N. C. Deno.; J. J. Jaruzelski.; Alan Schriesheim. An Acidity Function (C0) Derived from Arylcarbonium Ion Equilibria1. J. Am. Chem. Soc. 1955, 77, (11), 3044-3051.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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