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Bis(2,2,2-trifluoroethyl) phosphite was used in the synthesis of bis(2,2,2-trifluoroethyl phosphorochloridate. It was also employed as reagent for the synthesis of mono- and diesters of phosphorous acid.
Guy D. Joly.; Eric N. Jacobsen. Thiourea-Catalyzed Enantioselective Hydrophosphonylation of Imines:? Practical Access to Enantiomerically Enriched α-Amino Phosphonic Acids. J. Am. Chem. Soc. 2004, 126 (13),4102-4103.
Richard J Cohen.; Daniel L Fox.; Jarrod F Eubank.; Ralph Nicholas Salvatore. Mild and efficient Cs2CO3-promoted synthesis of phosphonates. Tetrahedron Lett. 2003, 44 (47),8617-8621.
Hazard Statements: H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210u-P261-P280a-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.