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H55752 Diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate, 98%

CAS Number
1149-23-1
Synonyms
1,4-Dihydro-2,6-dimethylpyridine-3,5-dicarboxylic acid diethyl ester

Stock No. Size Price ($) Quantity Availability
H55752-MD 250mg 20.10
H55752-03 1g 60.10
H55752-06 5g 204.00
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Diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate, 98%

MDL
MFCD00005951
EINECS
214-561-6

Chemical Properties

Formula
C13H19NO4
Formula Weight
253.30
Melting point
178-183°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in organic solvents.

Applications

Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is a hydrogen source in conjugate reduction and organocatalytic reductive amination. It is used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.

Notes

Desiccate at 4°C. Keep away from oxidizing agents.

Literature References

Hong Sheng Li.; Yi Qun Li. Potassium iodide catalyzed reductive dehalogenation of α-halo-ketones using Hantzsch ester diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate as reductant.Chin. Chem. Lett. 2010, 21 (8), 931-934.

E. A. Braude, (the late).; J. Hannah.; Reginald Linstead, Sir. 653. Hydrogen transfer. Part XVII. Homogeneous hydrogen transfer reactions from dihydrides of nitrogenous heterocycles to miscellaneous acceptors.J. Chem. Soc. 1960, (0),3257-3267.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2933.39
TSCA
No
RTECS
US7970100

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