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H56351 Azetidine, 98%

CAS Number
503-29-7
Synonyms

Stock No. Size Price ($) Quantity Availability
H56351-MD 250mg 41.20
H56351-03 1g 123.00
H56351-06 5g 506.00
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Azetidine, 98%

MDL
MFCD00005165
EINECS
207-963-8

Chemical Properties

Formula
C3H7N
Formula Weight
57.10
Boiling Point
61-62°
Flash Point
-21°(-6°F)
Density
0.847
Refractive Index
1.4320
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive.
Solubility
Miscible with water.

Applications

Azetidine is involved in a high yielding palladium-catalyzed cross-coupling reaction with aryl bromides. Further, it is used in Ullmann type coupling reaction with iodonitroflourenes. In addition to this, it reacts with bis-(3-amino-propyl)-amine to prepare N,N'-bis-(3-amino-propyl)-propanediyldiamine using palladium as a catalyst.

Notes

Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Air sensitive and heat sensitive. Incompatible with strong oxidizing agents and strong acids.

Literature References

Nassoy, A. C. M. A.; Raubo, P.; Harrity, J. P. A. Synthesis and indole coupling reactions of azetidine and oxetane sulfinate salts. Chem. Commun. 2015, 51 (27), 5914-5916.

Ding, F.; William, R.; Kock, S. M.; Leow, M. L.; Liu, X. W. A concise route to the highly-functionalized azetidine precursor: the enantioselective synthesis of penaresidin B. Chem. Commun. 2015, 51, 4639-4642.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
102384
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2933.99
TSCA
Yes

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