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590-97-6 - Bromomethyl acetate, 95% - Acetic acid bromomethyl ester - H56755 - Alfa Aesar

H56755 Bromomethyl acetate, 95%

CAS Number
590-97-6
Synonyms
Acetic acid bromomethyl ester

Size Price ($) Quantity Availability
5g 191.58
10g 306.94
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Bromomethyl acetate, 95%

MDL
MFCD00000170
EINECS
209-696-2

Chemical Properties

Formula
C3H5BrO2
Formula Weight
152.98
Boiling Point
130-133°
Flash Point
57°(135°F)
Density
1.56
Sensitivity
Moisture Sensitive
Solubility
Miscible with chloroform.

Applications

Bromomethyl acetate is involved in the preparation of optically active cyclohexene antisepsis agents. It acts as reagent in samarium diiodide-mediated conversion of ketones and aldehydes to 1,2-diacetates.

Notes

Store in cool place. Moisture sensitive and hygroscopic. Incompatible with strong oxidizing agents and strong bases.

Literature References

Pansuriya, P. B.; Parekh, H. M.; Maguire, G. E. M.; Friedrich, H. B. Tetramethoxy resorcin[4]arene-tetraester derivatives. J. Therm. Anal. Calorim. 2015, 120 (1), 653-665.

Neuenschwander, M. Low-Temperature Olefin Syntheses in View of Parent Fulvenes and Fulvalenes. Helv. Chim. Acta 2015, 98 (6), 731-762.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2915.39
TSCA
Yes
RTECS
AF6300200

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