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62673-31-8 - Benzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58014 - Alfa Aesar

H58014 Benzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
62673-31-8
Synonyms

Size Price ($) Quantity Availability
50ml 132.00
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Benzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671803

Chemical Properties

Formula
C7H7BrZn
Formula Weight
236.42
Density
0.978
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

It is applied in cross coupling reactions.

Notes

Air sensitive. Recommended storage temperature: 2 - 8°C.

Literature References

Ming Li.; Xiao-Xia Yan.; Wei Hong.; Xia-Zhen Zhu.; Bo-Xun Cao.; Jie Sun.; Xue-Long Hou. Palladium-Catalyzed Enantioselective Ring Opening of Oxabicyclic Alkenes with Organozinc Halides. Org. Lett. 2004, 6 (16),2833-2835.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

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