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H58185 alpha-Methylbenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
117892-77-0
Synonyms

Stock No. Size Price ($) Quantity Availability
H58185-AD 50ml 134.00
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alpha-Methylbenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Chemical Properties

Formula
C8H9ClZn
Formula Weight
206.00
Density
0.965
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Reacts with water.

Applications

It helps in the synyhesis of of heterotactic polylactic acid from rac-lactide.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Joëlle Char.; Emilie Brulé.; Philippe C. Gros.; Marie-Noelle Rager.; Vincent Guérineau.; Christophe M. Thomas. Synthesis of heterotactic PLA from rac-lactide using hetero-bimetallic Mg/Zn-Li systems.J. Organomet. Chem. 2015, 796 (1),47-52.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335-H336-H351

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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