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23665-09-0 - Phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58343 - Alfa Aesar

H58343 Phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
23665-09-0
Synonyms

Size Price ($) Quantity Availability
50ml 187.00
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Phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671995

Chemical Properties

Formula
C6H5IZn
Formula Weight
269.39
Density
0.966
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

It is used as primary and secondary intermediate.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Hidetoshi Tokuyam.; Satoshi Yokoshim.; Tohru Yamashita.; Tohru Fukuyama. A novel ketone synthesis by a palladium-catalyzed reaction of thiol esters and organozinc reagents. Tetrahedron Lett. 1998, 39 (20),3189-3192.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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