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131379-16-3 - 4-(Ethoxycarbonyl)phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58484 - Alfa Aesar

H58484 4-(Ethoxycarbonyl)phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
131379-16-3
Synonyms

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4-(Ethoxycarbonyl)phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD05664208

Chemical Properties

Formula
C9H9IO2Zn
Formula Weight
341.45
Density
1.023
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

4-(Ethoxycarbonyl)phenylzinc iodide is used as pharmaceutical intermediates.

Notes

Store at 4°C. Air Sensitive. Store under dry inert gas. Store away from air. Incompatible with oxidizing agents, bases. Protect from humidity and water. Do not together with acids.

Literature References

Laurin Melzig; Albrecht Metzger; Paul Knochel. Pd- and Ni-Catalyzed Cross-Coupling Reactions of Functionalized Organozinc Reagents with Unsaturated Thioethers. Chemistry - A European Journal.2011, 17 2948-2956.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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