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3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58498 - Alfa Aesar

H58498 3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
Synonyms

Size Price ($) Quantity Availability
50ml 289.00
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3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD11915899

Chemical Properties

Formula
C5H4BrNZn
Formula Weight
223.38
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

3-Pyridylzinc bromide used in coupling reaction.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Seung-Hoi Kim; Reuben D. Rieke. 2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction. Tetrahedron. 2010, 66 (17), 3135-3146.

Nadja M. Simkovsky; Monika Ermann; Stanley M. Roberts; David M. Parry; and Andy D. Baxter. Some regioselective cross-coupling reactions of halopyridines and halopyrimidines. J. Chem. Soc., Perkin Trans. 1. 2002, (16), 1847-1849.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
No

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